Graciela Arbilla de Klachquin
Instituição:
Universidade Federal do Rio de Janeiro
Centro:
Centro de Ciências Matemáticas e da Natureza
Unidade:
Instituto de Química
Departamento:
Departamento de Físico-Química/IQ
Formação:
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Universidad Nacional de Córdoba
Físico-Química | Doutorado | 1979 - 1982
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Universidad Nacional de Córdoba
Físico-Química | Graduação | 1973 - 1978
Laboratórios:
Nuvens de Palavras:
Artigos:
(69.43% artigos com DOI)
Titulo | DOI | Ano |
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Clean air for a good start: children are the future of the planet | 10.1590/1809-4422asoc20220004r1vu2023l1oa | 2023 |
Tijuca forest contribution to the improvement of air quality and wellbeing of citizens in the city of Rio de Janeiro, Brazil | 10.1016/j.chemosphere.2023.139017 | 2023 |
Determination of carbonyls and size-segregated polycyclic aromatic hydrocarbons, and their nitro and alkyl analogs in emissions from diesel-biodiesel-ethanol blends | 10.1007/s11356-023-26547-8 | 2023 |
Using mobile air quality station data to identify critical areas in the city of Rio de Janeiro regarding pollutant concentrations | 10.5327/Z2176-94781650 | 2023 |
Fine Particulate Matter: Brazilian Legislation in the Light of the World Health Organization Guidelines | 10.21577/1984-6835.20220082 | 2022 |
Evaluation of the Generation of Technofossils by Different Coffee Brewing Methods During COVID-19 Pandemic | 10.21577/1984-6835.20220025 | 2022 |
An improvement of method TO-15A, aided by heart-cutting multidimensional gas chromatography, for the analysis of C2-C12 hydrocarbons in atmospheric samples | 10.1016/j.microc.2022.108008 | 2022 |
An analysis of speciated hydrocarbons in hydrous ethanol (H100) and ethanol-gasoline blend (E22) for vehicle exhaust emissions | 10.1016/j.atmosenv.2022.119248 | 2022 |
Determination of size-segregated polycyclic aromatic hydrocarbon and its nitro and alkyl analogs in emissions from diesel-biodiesel blends | 10.1016/j.fuel.2020.118912 | 2021 |
Hydrocarbon emissions in flex fuel vehicles using ethanol: Preliminary results using a method implemented in Brazil | 10.1016/j.fuel.2020.119506 | 2021 |
Using mobility restriction experience for urban air quality management | 10.1016/j.apr.2021.101119 | 2021 |
A global observational analysis to understand changes in air quality during exceptionally low anthropogenic emission conditions | 10.1016/j.envint.2021.106818 | 2021 |
Benzene, Toluene, Ethylbenzene and Xylene (BTEX) Concentrations in Urban Areas Impacted by Chemical and Petrochemical Industrial Emissions | 10.1007/s00128-021-03336-y | 2021 |
Evaluation of Pedagogical Strategies used in the State of Rio de Janeiro for Teaching Chemistry, Physics and Biology in High School During the First Year of the COVID-19 Pandemic | 10.21577/1984-6835.20210073 | 2021 |
Understanding high tropospheric ozone episodes in Bangu, Rio de Janeiro, Brazil | 10.1007/s10661-020-8119-3 | 2020 |
A reactivity analysis of volatile organic compounds in a Rio de Janeiro urban area impacted by vehicular and industrial emissions | 10.1016/j.apr.2020.02.017 | 2020 |
Impact of the Petrochemical Complex on the Air Quality of an Urban Area in the City of Rio de Janeiro, Brazil | 10.1007/s00128-020-02802-3 | 2020 |
The impact of COVID-19 partial lockdown on the air quality of the city of Rio de Janeiro, Brazil | 10.1016/j.scitotenv.2020.139085 | 2020 |
Riscos no ar que respiramos | 2020 | |
Antropoceno: novo mundo, novo tempo | 2020 | |
Increased ozone levels during the COVID-19 lockdown: Analysis for the city of Rio de Janeiro, Brazil | 10.1016/j.scitotenv.2020.139765 | 2020 |
Preliminary Study of Ambiente Levels and Exposure to BTEX in the Rio de Janeiro Olympic Metropolitan Region, Brazil | 10.1007/s00128-020-02855-4 | 2020 |
RADIONUCLÍDEOS COMO MARCADORES DE UM NOVO TEMPO: O ANTROPOCENO | 10.21577/0100-4042.20170503 | 2020 |
COVID-19: challenges for a new epoch | 10.1590/0037-8682-0270-2020 | 2020 |
The Impact of COVID-19 Partial Lockdown on Primary Pollutant Concentrations in the Atmosphere of Rio de Janeiro and São Paulo Megacities (Brazil) | 10.1007/s00128-020-02907-9 | 2020 |
FATORES DE EMISSÃO DE COMPOSTOS CARBONÍLICOS MEDIDOS EM UM TÚNEL DO RIO DE JANEIRO, BRASIL, EM CONDIÇÕES REAIS DE DIRIGIBILIDADE | 10.21577/0100-4042.20170502 | 2020 |
The COVID-19 Pandemic: Living in the Anthropocene | 10.21577/1984-6835.20200081 | 2020 |
Online Chemistry Education Challenges for Rio de Janeiro Students during the COVID-19 Pandemic | 10.1021/acs.jchemed.0c00775 | 2020 |
MODELOS FOTOQUÍMICOS SIMPLES COMO FERRAMENTA PARA O GERENCIAMENTO DA QUALIDADE DO AR | 10.21577/0100-4042.20170343 | 2019 |
Levels of Volatile Carbonyl Compounds in the Atlantic Rainforest, in the City of Rio de Janeiro | 10.1007/s00128-019-02615-z | 2019 |
Why did ozone levels remain high in Rio de Janeiro during the Brazilian truck driver strike? | 10.1016/j.apr.2019.09.010 | 2019 |
The Updated Brazilian National Air Quality Standards: A Critical Review | 10.21577/0103-5053.20190212 | 2019 |
A minimum set of ozone precursor volatile organic compounds in an urban environment | 10.1016/j.apr.2017.11.002 | 2018 |
Efeitos da gestão de mobilidade urbana para os Jogos Olímpicos sobre a qualidade do ar na região central da cidade do Rio de Janeiro | 10.1590/2175-3369.010.supl1.ao07 | 2018 |
Antropoceno: Os Desafios de um Novo Mundo | 10.21577/1984-6835.20180111 | 2018 |
Urban planning and air quality. A case study: the role of Tijuca Forest in the city of Rio de Janeiro | 2018 | |
Polycyclic aromatic hydrocarbon patterns in the city of Rio de Janeiro | 10.1007/s11869-018-0566-4 | 2018 |
A Nova Idade Meghalayan: O que isso Significa para a Época do Antropoceno? | 10.21577/1984-6835.20180112 | 2018 |
Main Greenhouse Gases levels in the largest secondary urban forest in the world | 10.1016/j.apr.2018.10.009 | 2018 |
Floresta da Tijuca: uma floresta urbana no Antropoceno | 10.21577/1984-6835.20180117 | 2018 |
Simulação das trajetórias de poluentes em eventos naturais e antropogênicos | 10.21577/1984-6835.20180120 | 2018 |
A Química no Antropoceno | 10.21577/1984-6835.20180110 | 2018 |
Urbanização e os Desafios na Caracterização da Qualidade do Ar | 10.21577/1984-6835.20180122 | 2018 |
Air Quality in the Maracanã and Deodoro Zones During the Rio 2016 Olympic Games | 10.21577/0103-5053.20180099 | 2018 |
Poluição Atmosférica | 2017 | |
An Analytical Investigation of Ozone Episodes in Bangu, Rio de Janeiro | 10.1007/s00128-017-2041-6 | 2017 |
Chemical characterization of organosulfates from the hydroxyl radical-initiated oxidation and ozonolysis of cis -3-hexen-1-ol | 10.1016/j.atmosenv.2017.04.026 | 2017 |
Rate Coefficient for the Reaction of Cl Atoms with cis-3-Hexene at 296 ± 2 K | 10.21577/0103-5053.20170078 | 2017 |
Speciation Analysis of Ozone Precursor Volatile Organic Compounds in the Air Basins of the Rio de Janeiro Metropolitan Area | 10.21577/1984-6835.20170111 | 2017 |
Determination of Greenhouse Gases in Five Capitals in Different Brazilian Biomes | 10.21577/1984-6835.20170121 | 2017 |
Poluição Indoor | 2017 | |
Isoprene Emissions and Ozone Formation in Urban Conditions: A Case Study in the City of Rio de Janeiro | 10.1007/s00128-017-2248-6 | 2017 |
Air Quality Indexes in the City of Rio de Janeiro During the 2016 Olympic and Paralympic Games | 10.21577/0103-5053.20170226 | 2017 |
Isoprene, benzene and toluene levels at the major landmarks of Rio de janeiro during the 2014 FIFA World Cup | 10.20937/ATM.2016.29.03.02 | 2016 |
Avaliação da eficiência do Método TO-15 para determinação de compostos orgânicos voláteis em condições típicas de ambiente urbano | 10.21577/0100-4042.20160142 | 2016 |
Kinetic and mechanistic reactivity. Isoprene impact on ozone levels in an urban area near Tijuca Forest, Rio de Janeiro | 10.1007/s00128-016-1949-6 | 2016 |
Volatile Organic Compounds in the Atmosphere of the Botanical Garden of the City of Rio de Janeiro: A Preliminary Study | 10.1007/s00128-016-1887-3 | 2016 |
Rate coefficient for the reaction of OH radicals with cis-3-hexene: an experimental-theoretical study | 10.1039/c4cp05760k | 2015 |
Comparative Kinetics of the 3-Buten-1-ol and 1-Butene Reactions with OH Radicals: A Density Functional Theory/RRKM Investigation | 10.1021/jp512544x | 2015 |
Determination of CO2, CH4 and N2O: A Case Study for the city of Rio de Janeiro using a New Sampling Method | 10.5935/0103-5053.20150331 | 2015 |
Characterization of polycyclic aromatic hydrocarbon levels in the vicinity of a petrochemical complex located in a densely populated area of the Rio de Janeiro, Brazil | 10.5094/apr.2014.011 | 2014 |
Theoretical calculations of the kinetics of the OH reaction with 2-Methyl-2-Propen-1-ol and its Alkene Analogue | 10.1039/c4ra00695j | 2014 |
Theoretical Study of Δ-3-(+)-Carene Oxidation | 10.1039/C4CP02627F | 2014 |
PM2.5-Bound Polycyclic Aromatic Hydrocarbons in an Area of Rio de Janeiro, Brazil Impacted by Emissions of Light-Duty Vehicles Fueled by Ethanol-Blended Gasoline | 10.1007/s00128-014-1409-0 | 2014 |
Trace Metals in PM10 and PM2.5 Samples Collected in a Highly Industrialized Chemical/Petrochemical Area and Its Urbanized Surroundings | 10.1007/s00128-014-1219-4 | 2014 |
Alkyl polycyclic aromatic hydrocarbons emissions in diesel/biodiesel exhaust | 10.1016/j.atmosenv.2014.07.028 | 2014 |
The Impact of BTEX Emissions from Gas Stations into the Atmosphere | 10.5094/APR.2012.016 | 2012 |
Trace metals in the urban aerosols of Rio de Janeiro city | 10.1590/S0103-50532012000400007 | 2012 |
Carbonyl Oxides Reactions from Geraniol-trans-(3,7-dimethylocta-2,6-dien-1-ol), 6-Methyl-5-hepten-2-one, and 6-Hydroxy-4-methyl-4-hexenal Ozonolysis: Kinetics and Mechanisms | 10.1021/jp2014572 | 2011 |
Kinetics and Thermodynamics of Limonene Ozonolysis | 10.1021/jp205734h | 2011 |
Formaldehyde and acetaldehyde concentrations in the idle and taxiway areas of an urban airport | 10.1590/S0103-50532010000300013 | 2010 |
Volatile Organic Compounds in a Residential and Commercial Urban Area with a Diesel, Compressed Natural Gas and Oxygenated Gasoline Vehicular Fleet. | 10.1007/s00128-009-9886-2 | 2010 |
Comparative Study of Automotive, Aircraft and Biogenic Emissions of Aldehydes and Aromatic Compounds | 10.1007/s00128-009-9891-5 | 2010 |
Evolution of Particulate Matter and Associated Metal Levels in the Urban Area of Rio de Janeiro, Brazil | 10.1007/s00128-009-9931-1 | 2010 |
Pattern of volatile aldehydes and aromatic hydrocarbons in the largest urban rainforest in the Americas | 10.1016/j.chemosphere.2010.03.028 | 2010 |
Five-years of Formaldehyde and Acetaldehyde Monitoring in the Rio de Janeiro Downtown Area | 10.1016/j.atmosenv.2010.03.043 | 2010 |
Theoretical Study of the OH Addition to Geraniol-trans (3,7-dimethylocta-2,6-dien-1-ol), 6-methyl-5-hepten-2-one, and 6-hydroxy-4-methyl-4-hexenal | 10.1021/jp911499y | 2010 |
Particle-associated polycyclic aromatic hydrocarbons in a suburban region of Rio de Janeiro, Brazil | 10.1590/S0103-50532009000300017 | 2009 |
Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro Metropolitan Area, Brazil | 10.1590/S0103-50532009000900002 | 2009 |
Determinação de metais traço devidos à produção e uso de diesel através do monitoramento da qualidade do ar de áreas impactadas | 2009 | |
Analysis of the impact of emissions from the petrochemical complex in Campos Elíseos on the air quality of Air Basin III | 2009 | |
Concentration of airbone trace metals in a bus station with a high heavy-duty diesel fraction | 10.1590/s0103-50532009000700020 | 2009 |
Atmospheric concentrations and dry deposition fluxes of particulate trace metals in Salvador, Bahia, Brazil | 10.1016/j.atmosenv.2007.06.013 | 2008 |
Theoretical investigation of the gas phase oxidation mechanism of dimethyl sulfoxide by OH radical | 10.1016/j.theochem.2007.09.027 | 2008 |
Principais carbonilas no ar de locais públicos no Rio de Janeiro | 10.1590/S0100-40422008000200011 | 2008 |
Carbonyls emissions in diesel and biodiesel exhaust | 10.1016/j.atmosenv.2007.09.073 | 2008 |
Primary emission ratios obtained from the monitoring of criteria pollutants in Rebouças Tunnel, Rio de Janeiro, Brazil | 2008 | |
Ozonolysis of geraniol-trans, 6-methyl-5-hepten-2-one and 6-hydroxy-4-methyl-4-hexenal: kinetics and mechanism | 10.1021/jp8027534 | 2008 |
Mercaptans emissions in diesel and biodiesel exhaust | 10.1016/j.atmosenv.2008.05.036 | 2008 |
Oxidation mechanism of dimethyl sulfoxide (DMSO) by OH radical in liquid phase | 10.1039/b810384d | 2008 |
Theoretical investigation of the stability of ionic formic acid clusters | 10.1021/jp807792s | 2008 |
Emissões de poluentes não legislados por biodiesel | 2008 | |
Evaluation of levels, sources and distribution of toxic elements in PM10 in a suburban industrial region, Rio de Janeiro, Brazil | 10.1007/s10661-007-9815-y | 2008 |
A two-year monitoring program of aromatic hydrocarbons in Rio de Janeiro downtown area | 10.1590/S0103-50532007000300007 | 2007 |
Atmospheric levels of aldehydes and BTEX and their relationship with vehicular fleet changes in Rio de Janeiro urban area | 10.1016/j.chemosphere.2006.09.088 | 2007 |
Experimental and theoretical study of the air quality in a suburban industrial-residential area in Rio de Janeiro, Brazil | 10.1590/S0103-50532007000200015 | 2007 |
Impact of aircraft traffic emissions on ozone formation at the Rio de Janeiro urban area | 2007 | |
Volatile aromatic compounds in a light-duty vehicle tunnel in Rio de Janeiro, Brazil | 10.1007/s00128-007-9171-1 | 2007 |
Exposure to volatile organic compounds in an ethanol and gasoline service station | 10.1007/s00128-007-9181-z | 2007 |
Spatial distribution of polycyclic aromatic hydrocarbons in Terminalia catappa L. (Combretaceae) bark from a selected heavy road traffic area of Rio de Janeiro City, Brazil | 10.1016/j.jhazmat.2006.08.034 | 2007 |
Avaliação da poluição ambiental causada por particulado de chumbo emitido por uma reformadora de baterias na cidade do Rio de Janeiro, Brasil | 10.1590/S0102-311X2006000900012 | 2006 |
Concentration and emission sources of airborne metals in particulate matter in the industrial district of Médio Paraíba, State of Rio de Janeiro, Brazil | 10.1007/S00244-005-0313-3 | 2006 |
Aromatic hydrocarbons emissions in diesel and biodiesel exhaust | 10.1016/j.atmosenv.2006.05.068 | 2006 |
Polyciclic aromatic hydrocarbons and their molecular diagnostic ratios in airborne particles (PM10) collected in Rio de Janeiro, Brazil | 10.1007/s11270-006-9215-x | 2006 |
Emissões de formaldeído e acetaldeído de misturas biodiesel/diesel | 2006 | |
Characterization of Airborne Trace Metal Distribution in Baixada Fluminense, Rio de Janeiro, Brazil, by Operational Speciation | 10.1007/s00128-006-1040-9 | 2006 |
Theoretical study of fluorination reaction by diethylaminosulfur trifluoride (DAST) | 10.1016/j.theochem.2006.01.002 | 2006 |
Particulate Matter and Associated Metal Levels in a Conservation Area in the Remaining Tropical Forest of Mata Atlântica, Brazil | 10.1007/s00128-006-1112-x | 2006 |
Evaluation of reaction thermochemistry using DFT calculated molecular properties: Application to trans-HONO = HO + NO | 10.1590/S0103-50532005000200010 | 2005 |
Evaluation of levels, sources and distribution of airborne trace metals in seven districts of the Baixada Fluminense, Rio de Janeiro, Brazil | 10.1016/j.atmosenv.2005.02.030 | 2005 |
Formaldehyde and acetaldehyde associated with the use of natural gas as a fuel for light vehicles | 10.1016/j.atmosenv.2005.03.042 | 2005 |
Assessment of the concentrations and emission sources of airborne metals in particulate matter in seven Districts of Baixada Fluminense, Rio de Janeiro | 10.1007/s00128-005-0848-z | 2005 |
PAHs diurnal and nocturnal samples of total suspended particulate in a high trafficked area of Rio de Janeiro city, Brazil | 10.1007/s00128-005-0849-y | 2005 |
Metals in airborne particulate matter in the Industrial District of Santa Cruz, Rio de Janeiro, in an annual period | 10.1016/j.atmosenv.2003.09.017 | 2004 |
Aromatic volatile organic compounds emissions in a tire recapping unit | 10.1007/s00128-003-8686-3 | 2004 |
Metals in Airborne Particulate Matter in Downtown Rio de Janeiro, Brazil | 10.1007/s00128-004-0331-2 | 2004 |
Formaldehyde and acetaldehyde in a high traffic street of Rio de Janeiro, Brazil | 10.1016/s1352-2310(02)00805-1 | 2003 |
Computer modeling study of ethanol and aldheydes reactivities in Rio de Janeiro urban air | 10.1016/s1352-2310(03)00081-5 | 2003 |
Controle das emissões de chumbo particulado no entorno de uma reformadora de baterias da cidade do Rio de Janeiro usando ar como indicador | 10.1590/S0102-311X2003000200014 | 2003 |
Unimolecular Reactions of Formaldehyde So PES | 2002 | |
Polyciclic Aromatic Hydrocarbons in Leachate from a Municipal Solid Waste Dump of Niterói City, RJ, Brazil | 2002 | |
Determination of PCDD/F in total suspended particles in Rio de Janeiro: A preliminary study | 2002 | |
Polyciclic aromatic hydrocarbons in total suspended particulate of Niterói, RJ, Brazil: A comparison of summer and winter samples | 2002 | |
Ozone Air Quality Modeling. A Case Study: A Heavily Vehicle Impacted Urban Avenue in Rio de Janeiro, Brazil | 10.1590/s0103-50532002000300004 | 2002 |
Theoretical study and rate constants for the unimolecular isomerization of YONO (Y=F, Cl and Br) | 2001 | |
Preliminary Comparison for PAH in Total Suspended particulate Samples taken at Niteroi and Rio de Janeiro, Brazil | 2001 | |
Kinetic analysis of the chemical processes in the decomposition of gaseous dielectrics by a non-equilibrium plasma. Part I: CF4 and CF4/O2 mixtures | 2000 | |
Kinetic analysis of the chemical processes in the decomposition of gaseous dielectrics by a non-equilibrium plasma. Part II: SF6 and SF6/O2 mixtures | 2000 | |
Reaction Coordinate and rate constants for nitrous acid cis- trans- isomerization | 2000 | |
Avaliação da Contaminação Humana por Hidrocarbonetos Policíclicos Aromáticos (HPAs) e seus Derivados Nitrados: Uma Revisão Metodológica | 2000 | |
Theoretical Study of the CF2=CH2 = HF + CFCH Reaction | 2000 | |
Simulation of air pollution from mobile source emissions in Rio de Janeiro City | 1999 | |
Otimização de um mecanismo fotoquímico para a simulação da atmosfera urbana brasileira | 1999 | |
Kinetic analysis of the gas-phase reactions of methacrolein with the OH radical in the presence of NOx | 1999 | |
Modelagem dos processos químicos em plasmas de misturas gasosas usadas na corrosão de silício. Parte 1: CF4/O2 | 1998 | |
Modelagem dos processos químicos em plasmas de misturas gasosas usadas na corrosão de silício. Parte 2: SF6/O2 | 1998 | |
Cinética não isotérmica na análise térmica de sólidos | 1998 | |
Modeling and separation or rare earth elements by counter current electromigration. A new separation column | 1998 | |
Kinetic analysis of the gas phase reactions of methyl-ter-butyl-ether with OH radicals in the presence of NOx | 1998 | |
The unimolecular decomposition of formaldheyde: H2CO = H2 + CO. Part 1: Ab-initio reaction path and variational transition state rate constants | 1998 | |
Kinetic analysis of the gas-phase reactions of methyl vinyl ketone wit the OH radical in the presence of NOx | 1998 | |
Simulação da química da atmosfera poluída por automóveis movidos alcool | 1997 | |
Modelagem numérica de sistemas cinéticos complexos | 1996 | |
Modelo numérico para as reações químicas do ozônio na estratosfera | 1996 | |
Terras raras, dominando a tecnologia de materiais estratégicos | 1996 | |
Técnicas Computacionais em Química | 1994 | |
Kinetic Modelling of the Photodecomposition of Ketene | 1993 | |
Collisional Energy Transfer of Highly Excited Polyatomic Molecules. A Statistical Point of View | 1993 | |
Calculated RRKM Rate Constants for Competitive Reactions | 1992 | |
The Unimolecular Decomposition and Isomerization of Chemically Activated 1-methyl-2,2,3,3-tetrafluorocyclopropane | 1992 | |
Photodecomposition of Ketene in the Presence of a Continuous Electric Field | 1991 | |
Intramolecular Perturbations in Small Molecules in the Presence of a Continuous Electric Field | 1991 | |
Multistep Collisional Deactivation of Highly Vibrationally Excited 1,1,2-trifluoro-2-trifluoromethylcyclopropane | 1990 | |
Electric Field Effect on the Chemical Activation Processes of 1,1,2,2-tetrafluorocyclopropane | 1990 | |
The Decomposition of 1,1,2,2-tetrafluorocyclopropane. Arrhenius Parameters and their Influence on the Chemical Activation Results | 1989 | |
Vibrational Energy Transfer Probabilities of Highly Excited 1,1,2,2-tetrafluorocyclopropane | 1984 | |
Multistep Collisional Deactivation of Highly Vibrational Excited 1,1,2,2-tetrafluorocyclopropane | 1983 |
Eventos:
(0.00% eventos com DOI)