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desenvolvimento caracterizacao acylhydrazone derivatives herpes simplex occidentalis extract human inhibitor sobre virus calculations snake venom contendo caracterizacao nanoparticulas glycosaminoglycans complexo bothrojaracin copper transform infrared properties anticoagulant virus herpes characterization vitro sulfated galactan fucosylated chondroitin sulfated polysaccharide heparin bothrops jararaca activity sulfated spectra derived